By Albert Lyngzeidetson
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Additional info for BarCharts QuickStudy Psychology of Relationships
Open circles are observed values for polycrystalline EuBa&u@-, to be compared. The curve calculated in the free-ion model (dashed curve, El = 390 K = E,/3, I’, = V4 = 0) fits data insufficiently. The obtained values of El and Ez are rather small compared with those of other Eu3+ compounds [88Y 13;for details and magnetic susceptibility comparison of SC and NSC compounds seeoriginal paper; for magnetic susceptibility above 300 K see[87Jl]; for magnetic susceptibility of EuBa,(Cui -XZnX)306+y compound see [87Gl].
Such kink is expected at AF transitions of a quadratic Heisenberg antiferromagnet [74J]. 6, a rapid increase of susceptibility is observed, as in [88MlO]. This increase of x is mainly due to Cu in the Cu(1) site (Cu in the Cu-0 chain). Solid lines are guide lines [89Y2]. 18 0 100 200 300 400 5 40’ ~m3 -1 500 K 600 I YbCu&~ I semicon. i*+ supercon. 6 core diom. 2 0 -6 Fig. 53. YBa,Cu,O,-s. Intrinsic magnetic mass susceptibility vs. oxygen content at 600 K. The values for xf” are obtained from measured values being corrected for the susceptibility due to the paramagnetic Cu2+ ions in Cu(1) site.
2 Magnetic susceptibilities and concentration 21 Gcm3 9 phase diagrams I I 53 I I oooo co. GdBa2(Cul-,Ni,)307-, I I % ^I I 8 0 Ni Zn l 30 K Fig. 84. l)307-,. Reciprocal susceptibility vs. temperature for Ni- or Zn-substituted compounds. The solid line is a guide to the eye. A deviation from the Curie-Weiss behavior occurs at about 8 K for both Ni- and Zn-substituted compounds. No such deviation was observed for oxygendeficient NSC GdBazCu307 -y [9OC3]. 5 Fig. 85. GdBaJCui -xNix)307-y. Specific magnetization Qin a magnetic field of 10 kOe vs.